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Two decades later this concept was generalized by Lifshitz in order to derive a complete scheme able to grasp the origin of van der Waals dispersion forces between solid bodies The metal vacuum interface (the surface charge density near metal) can be described with the free-electron Sommerfeld approximation (FESA) where the ground-state properties of the electron gas are obtained by lling up the conduction band with N free electrons obeying a Fermi Dirac distribution This free-electron scheme can be completed by applying the density functional method inside a jellium environment in which the ion cores are smeared out into a uniform positive background truncated by the surface The electron charge pro le near various metal surfaces was calculated with this technique by Lang and Kohn It shows up the splitting between delocalized electronic charges and positive jellium into the vacuum side of the interface.

In the metal, it exhibits the well-known Friedel oscillations, which have the characteristic wavelength /KF (KF is the Fermi wave vector) One can calculate the permanent and probabilistic near- eld component of the electronic wave function associated with the FESA electrons The exponential nature of the evanescent wave function provides the opportunity for a uniquely sensitive form of microscopy Exploitation of this simple electronic decay law began with the invention of the STM by Binnig and Rohrer in 1981; since then, exploitation of this e ect has enabled many original studies at subnanoscale resolution to be undertaken..

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If you don t want to do something, say so. Whether it is something your mate asks you to do or something your boss tells you to do, don t agree to do it just to get him or her off your back. You ll only end up putting it off or lying about working on it when you have no intention of doing so. You may have been raised to believe that it wasn t safe to stand up to others, but now you are an adult and you need to remind yourself that nothing horrible is going to happen to you if you say no. (If you are in an abusive relationship, this may not be completely true. You may need to get out of the relationship so that you are not in danger.) If you don t feel like an adult or feel too inadequate to stand up for yourself, the only way you re going to feel stronger is by doing it. Start with less risky no s and work your way up. If your partner or your boss or whoever you feel intimidated by gets upset, so be it. Let him get upset. Let her rant and rave if she wants to. The more you stand up for yourself and the more you say how you honestly feel, the

Figure 6.36. Free interface diffusion. This is generally similar to microdialysis except no membrane is used. Concentration gradients are generated at the interface which gives local supersaturation. The technique is particularly useful in microgravity.

This lets you print out the contents of the shadow password file if you are a member of group shadow. (And you shouldn t be. It s a huge security risk to let anyone except a few key programs have access to the etc/shadow file.)

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